Nice project and good luck! Did you already brumate them? If not , that needs to happen to give the sex cells time to mature. It also is a natural behavior that prepares the snakes psychologically as well as physically to breed. It's good that you are 100% sure of the sexes. If you have brumated them then it's just a matter of which female is actively sending out (by scent) the pheromonal triggers to the male. That usually can be immediate but more than likely occurs after the female sheds out.